The ocean takes up around a quarter of the carbon dioxide (CO₂) that human activity releases into the air each year. In seawater, this CO₂ changes the water's carbonate chemistry and lowers its pH, a process called ocean acidification. The surface ocean has not become acidic in absolute terms, but it is moving in that direction: global average surface pH fell from 8.11 in 1985 to 8.04 in 2024, an increase in acidity of about 18%, and the World Meteorological Organization (WMO) reports a steady decline of about 0.017 pH units per decade from 1985 to 2025. Since the start of the industrial era, surface pH has fallen by around 0.1 units, or 30–40% more acidity, and the Intergovernmental Panel on Climate Change (IPCC) has very high confidence that today's values are unprecedented for at least 26,000 years. The main cause is CO₂ from fossil fuels; atmospheric CO₂ reached 422.1 parts per million in 2024, more than 50% above the pre-industrial level.
Acidification makes it harder for organisms that build shells and skeletons from calcium carbonate, such as corals, oysters, mussels and tiny swimming sea snails called pteropods, to form and keep them. Pteropods, an important food source in marine food webs, already show signs of shell damage. A 2025 study estimates that between pre-industrial times and 2020 the change in ocean chemistry cut suitable habitat by 43% for tropical and subtropical coral reefs, by up to 61% for polar pteropods and by 13% for coastal bivalves such as oysters and clams. The only documented population die-offs so far are of Pacific oyster larvae at hatcheries on the west coast of North America, where acidification added to naturally corrosive upwelled water. Cold-water corals, tropical reefs and Arctic marine life are considered especially at risk, with knock-on effects for coastal fisheries, food security and the communities that depend on them. Acidification acts together with ocean warming and loss of oxygen, and the effects of the three combined are still poorly understood.